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Photodissociation dynamics of iodocyclohexane upon UV excitation by femtosecond pump-probe technique
Hu, Chunlong; Wang, Lian; Wang, Yanmei; Tang, Ying; Long, Jinyou; Zhang, Bing1
2016-08-01
Source PublicationCHEMICAL PHYSICS LETTERS
Volume658Pages:134-139
SubtypeArticle
AbstractThe photodissociation dynamics of iodocyclohexane in the A-band and C-state have been investigated by femtosecond time-resolved time-of-flight mass spectroscopy. lodocyclohexane was pumped by 266 nm pulse to its A-band. The following dissociation dynamics is prompt and direct. The time it takes for the progression of the wave packet from the dissociative state to the dissociating asymptotic region is around 180 fs. The C-state was excited by 200 nm pump pulse and it has predissociative character with predissociation time of about 600 fs, which may have contributions from multiple vibrational modes. (C) 2016 Elsevier B.V. All rights reserved.
KeywordIodocyclohexane Pump-probe Femtosecond Lifetime Photodissociation Predissociation
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1016/j.cplett.2016.06.034
WOS KeywordPHOTOFRAGMENT TRANSLATIONAL SPECTROSCOPY ; OZONE DEPLETION ; METHYL-IODIDE ; SPECTRA ; TROPOSPHERE ; IONIZATION ; CHEMISTRY ; RADICALS ; BAND
Indexed BySCI
Language英语
WOS Research AreaChemistry ; Physics
WOS SubjectChemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS IDWOS:000382409800023
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.wipm.ac.cn/handle/112942/9582
Collection原子分子光物理研究部
Affiliation1.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Hu, Chunlong,Wang, Lian,Wang, Yanmei,et al. Photodissociation dynamics of iodocyclohexane upon UV excitation by femtosecond pump-probe technique[J]. CHEMICAL PHYSICS LETTERS,2016,658:134-139.
APA Hu, Chunlong,Wang, Lian,Wang, Yanmei,Tang, Ying,Long, Jinyou,&Zhang, Bing.(2016).Photodissociation dynamics of iodocyclohexane upon UV excitation by femtosecond pump-probe technique.CHEMICAL PHYSICS LETTERS,658,134-139.
MLA Hu, Chunlong,et al."Photodissociation dynamics of iodocyclohexane upon UV excitation by femtosecond pump-probe technique".CHEMICAL PHYSICS LETTERS 658(2016):134-139.
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