APM OpenIR
Construction of a functionalized hierarchical pore metal-organic framework via a palladium-reduction induced strategy
Xiao, Yue-Yang1; Liu, Xiao-Long2; Chang, Gang-Gang1; Pu, Chun1; Tian, Ge1; Wang, Li-Ying3; Liu, Jia-Wen1; Ma, Xiao-Chen1; Yang, Xiao-Yu1; Chen, Banglin4
2020-03-21
Source PublicationNANOSCALE
ISSN2040-3364
Volume12Issue:11Pages:6250-6255
AbstractHierarchical porosity and functionalization are recognized as two crucial parameters in mediating the catalytic performance of heterogeneous catalysts, however, they are rarely achieved simultaneously in the development of metal-organic frameworks (MOFs). In this work, a simple and efficient method has been developed to synchronously construct hierarchical porosity and functionalization within a sulfonic acid group functionalized microporous MOF via a palladium-reduction induced strategy, for the first time. The generation mechanism of the mesopore has been explained using two-dimensional H-1 DQ-SQ MAS NMR. The content of the mesopore and the active sites within mesoPd@NUS-6 could be finely tuned by simply controlling Pd loading. Particularly, the combination of hierarchical porosity and functionalization, as well as the ultra-stable structure endow the composites with great potential in bulk, for adsorption and heterogeneous catalysis.
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China
DOI10.1039/c9nr10092j
WOS KeywordEFFICIENT ; NANOPARTICLES ; MOFS ; ADSORPTION ; SEPARATION ; CATALYSIS ; HAFNIUM ; FACILE ; DESIGN ; SIZE
Language英语
Funding ProjectNational Natural Science Foundation of China[21706199] ; National Natural Science Foundation of China[U1662134] ; National Natural Science Foundation of China[51861135313]
Funding OrganizationNational Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS SubjectChemistry, Multidisciplinary ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied
WOS IDWOS:000522124800005
PublisherROYAL SOC CHEMISTRY
Citation statistics
Document Type期刊论文
Identifierhttp://ir.apm.ac.cn/handle/112942/22316
Collection中国科学院武汉物理与数学研究所
Corresponding AuthorChang, Gang-Gang; Chen, Banglin
Affiliation1.Wuhan Univ Technol, Sch Chem Chem Engn & Life Sci, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Hubei, Peoples R China
2.Sun Yat Sen Univ, Guangzhou 510275, Peoples R China
3.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Hubei, Peoples R China
4.Univ Texas, Dept Chem, One UTSA Circle, San Antonio, TX 78249 USA
Recommended Citation
GB/T 7714
Xiao, Yue-Yang,Liu, Xiao-Long,Chang, Gang-Gang,et al. Construction of a functionalized hierarchical pore metal-organic framework via a palladium-reduction induced strategy[J]. NANOSCALE,2020,12(11):6250-6255.
APA Xiao, Yue-Yang.,Liu, Xiao-Long.,Chang, Gang-Gang.,Pu, Chun.,Tian, Ge.,...&Chen, Banglin.(2020).Construction of a functionalized hierarchical pore metal-organic framework via a palladium-reduction induced strategy.NANOSCALE,12(11),6250-6255.
MLA Xiao, Yue-Yang,et al."Construction of a functionalized hierarchical pore metal-organic framework via a palladium-reduction induced strategy".NANOSCALE 12.11(2020):6250-6255.
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