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Photoelectron spectroscopy of aqueous solutions: Streaming potentials of NaX (X = Cl, Br, and I) solutions and electron binding energies of liquid water and X-
Kurahashi, Naoya1,2,3; Karashima, Shutaro1,2; Tang, Ying1,3,4; Horio, Takuya1,2,3; Abulimiti, Bumaliya2,4; Suzuki, Yoshi-Ichi1,2; Ogi, Yoshihiro2; Oura, Masaki5; Suzuki, Toshinori1,2,3
2014-05-07
Source PublicationJOURNAL OF CHEMICAL PHYSICS
Volume140Issue:17
SubtypeArticle
AbstractThe streaming potentials of liquid beams of aqueous NaCl, NaBr, and NaI solutions are measured using soft X-ray, He(I), and laser multiphoton ionization photoelectron spectroscopy. Gaseous molecules are ionized in the vicinity of liquid beams and the photoelectron energy shifts are measured as a function of the distance between the ionization point and the liquid beam. The streaming potentials change their polarity with concentration of electrolytes, from which the singular points of concentration eliminating the streaming potentials are determined. The streaming currents measured in air also vanish at these concentrations. The electron binding energies of liquid water and I-, Br-, and Cl- anions are revisited and determined more accurately than in previous studies. (C) 2014 AIP Publishing LLC.
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1063/1.4871877
WOS KeywordMOLECULAR-BEAM ; PHOTOEMISSION ; EVAPORATION ; MICROJETS ; DYNAMICS ; SPECTRUM ; CHARGE ; JETS
Indexed BySCI
Language英语
WOS Research AreaPhysics
WOS SubjectPhysics, Atomic, Molecular & Chemical
WOS IDWOS:000336048000029
Citation statistics
Cited Times:43[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.wipm.ac.cn/handle/112942/1462
Collection原子分子光物理研究部
Affiliation1.Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan
2.RIKEN, Mol React Dynam Res Team, RIKEN Ctr Adv Photon, Wako, Saitama 3510198, Japan
3.Japan Sci & Technol Agcy, CREST, Chiyoda Ku, Tokyo 1020076, Japan
4.Chinese Acad Sci, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China
5.5RIKEN SPring 8 Ctr, Sayo, Hyogo 6795148, Japan
Recommended Citation
GB/T 7714
Kurahashi, Naoya,Karashima, Shutaro,Tang, Ying,et al. Photoelectron spectroscopy of aqueous solutions: Streaming potentials of NaX (X = Cl, Br, and I) solutions and electron binding energies of liquid water and X-[J]. JOURNAL OF CHEMICAL PHYSICS,2014,140(17).
APA Kurahashi, Naoya.,Karashima, Shutaro.,Tang, Ying.,Horio, Takuya.,Abulimiti, Bumaliya.,...&Suzuki, Toshinori.(2014).Photoelectron spectroscopy of aqueous solutions: Streaming potentials of NaX (X = Cl, Br, and I) solutions and electron binding energies of liquid water and X-.JOURNAL OF CHEMICAL PHYSICS,140(17).
MLA Kurahashi, Naoya,et al."Photoelectron spectroscopy of aqueous solutions: Streaming potentials of NaX (X = Cl, Br, and I) solutions and electron binding energies of liquid water and X-".JOURNAL OF CHEMICAL PHYSICS 140.17(2014).
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