APM OpenIR
Hierarchical CdS/m-TiO2/G ternary photocatalyst for highly active visible light-induced hydrogen production from water splitting with high stability
Lu, Yi1; Cheng, Xiu1; Tian, Ge1; Zhao, Heng1; He, Li1; Hu, Jie1; Wu, Si-Ming1; Dong, Ying1; Chang, Gang-Gang1; Lenaerts, Silvia2; Siffert, Stephane3; Van Tendeloo, Gustaaf4; Li, Zhao-Fei5; Xu, Ling-Ling6; Yang, Xiao-Yu1; Su, Bao-Lian1,7
2018-05-01
Source PublicationNANO ENERGY
ISSN2211-2855
Volume47Pages:8-17
SubtypeArticle
AbstractHierarchical semiconductors are the most important photocatalysts, especially for visible light-induced hydrogen production from water splitting. We demonstrate herein a hierarchical electrostatic assembly approach to hierarchical CdS/m-TiO2/G ternary photocatalyst, which exhibits high photoactivity and excellent photostability (more than twice the activity of pure CdS while 82% of initial photoactivity remained after 15 recycles during 80 h irradiation). The ternary nanojunction effect of the photocatalyst has been investigated from orbitals hybrid, bonding energy to atom-stress distortion and nano-interface fusion. And a coherent separation mechanism of charge carriers in the ternary system has been proposed at an atomic/nanoscale. This work offers a promising way to inhibit the photocorrosion of CdS and, more importantly, provide new insights for the design of ternary nanostructured photocatalysts with an ideal heterojunction.
KeywordCds Mesoporous Tio2 Graphene Sheets Ternary Photocatalysis Visible Light-induced Water Splitting
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
Funding OrganizationNational Key R&D Program of China(2017YFC1103800) ; National Key R&D Program of China(2017YFC1103800) ; Program for Changjiang Scholars and Innovative Research Team in University(IRT_15R52) ; Program for Changjiang Scholars and Innovative Research Team in University(IRT_15R52) ; National Natural Science Foundation of China(U1663225 ; National Natural Science Foundation of China(U1663225 ; International Science & Technology Cooperation Program of China(2015DFE52870) ; International Science & Technology Cooperation Program of China(2015DFE52870) ; Natural Science Foundation of Hubei Province(2016CFA033 ; Natural Science Foundation of Hubei Province(2016CFA033 ; Open Project Program of State Key Laboratory of Petroleum Pollution Control CNPC Research Institute of Safety and Environmental Technology(PPC2016007) ; Open Project Program of State Key Laboratory of Petroleum Pollution Control CNPC Research Institute of Safety and Environmental Technology(PPC2016007) ; China Postdoctoral Science Foundation(2016M592400) ; China Postdoctoral Science Foundation(2016M592400) ; Fundamental Research Funds for the Central Universities(WUT: 2017IVB012) ; Fundamental Research Funds for the Central Universities(WUT: 2017IVB012) ; U1662134 ; U1662134 ; 2017CFB487) ; 2017CFB487) ; 51472190 ; 51472190 ; 51611530672 ; 51611530672 ; 21711530705 ; 21711530705 ; 51503166 ; 51503166 ; 51602236 ; 51602236 ; 21706199) ; 21706199) ; National Key R&D Program of China(2017YFC1103800) ; National Key R&D Program of China(2017YFC1103800) ; Program for Changjiang Scholars and Innovative Research Team in University(IRT_15R52) ; Program for Changjiang Scholars and Innovative Research Team in University(IRT_15R52) ; National Natural Science Foundation of China(U1663225 ; National Natural Science Foundation of China(U1663225 ; International Science & Technology Cooperation Program of China(2015DFE52870) ; International Science & Technology Cooperation Program of China(2015DFE52870) ; Natural Science Foundation of Hubei Province(2016CFA033 ; Natural Science Foundation of Hubei Province(2016CFA033 ; Open Project Program of State Key Laboratory of Petroleum Pollution Control CNPC Research Institute of Safety and Environmental Technology(PPC2016007) ; Open Project Program of State Key Laboratory of Petroleum Pollution Control CNPC Research Institute of Safety and Environmental Technology(PPC2016007) ; China Postdoctoral Science Foundation(2016M592400) ; China Postdoctoral Science Foundation(2016M592400) ; Fundamental Research Funds for the Central Universities(WUT: 2017IVB012) ; Fundamental Research Funds for the Central Universities(WUT: 2017IVB012) ; U1662134 ; U1662134 ; 2017CFB487) ; 2017CFB487) ; 51472190 ; 51472190 ; 51611530672 ; 51611530672 ; 21711530705 ; 21711530705 ; 51503166 ; 51503166 ; 51602236 ; 51602236 ; 21706199) ; 21706199) ; National Key R&D Program of China(2017YFC1103800) ; National Key R&D Program of China(2017YFC1103800) ; Program for Changjiang Scholars and Innovative Research Team in University(IRT_15R52) ; Program for Changjiang Scholars and Innovative Research Team in University(IRT_15R52) ; National Natural Science Foundation of China(U1663225 ; National Natural Science Foundation of China(U1663225 ; International Science & Technology Cooperation Program of China(2015DFE52870) ; International Science & Technology Cooperation Program of China(2015DFE52870) ; Natural Science Foundation of Hubei Province(2016CFA033 ; Natural Science Foundation of Hubei Province(2016CFA033 ; Open Project Program of State Key Laboratory of Petroleum Pollution Control CNPC Research Institute of Safety and Environmental Technology(PPC2016007) ; Open Project Program of State Key Laboratory of Petroleum Pollution Control CNPC Research Institute of Safety and Environmental Technology(PPC2016007) ; China Postdoctoral Science Foundation(2016M592400) ; China Postdoctoral Science Foundation(2016M592400) ; Fundamental Research Funds for the Central Universities(WUT: 2017IVB012) ; Fundamental Research Funds for the Central Universities(WUT: 2017IVB012) ; U1662134 ; U1662134 ; 2017CFB487) ; 2017CFB487) ; 51472190 ; 51472190 ; 51611530672 ; 51611530672 ; 21711530705 ; 21711530705 ; 51503166 ; 51503166 ; 51602236 ; 51602236 ; 21706199) ; 21706199) ; National Key R&D Program of China(2017YFC1103800) ; National Key R&D Program of China(2017YFC1103800) ; Program for Changjiang Scholars and Innovative Research Team in University(IRT_15R52) ; Program for Changjiang Scholars and Innovative Research Team in University(IRT_15R52) ; National Natural Science Foundation of China(U1663225 ; National Natural Science Foundation of China(U1663225 ; International Science & Technology Cooperation Program of China(2015DFE52870) ; International Science & Technology Cooperation Program of China(2015DFE52870) ; Natural Science Foundation of Hubei Province(2016CFA033 ; Natural Science Foundation of Hubei Province(2016CFA033 ; Open Project Program of State Key Laboratory of Petroleum Pollution Control CNPC Research Institute of Safety and Environmental Technology(PPC2016007) ; Open Project Program of State Key Laboratory of Petroleum Pollution Control CNPC Research Institute of Safety and Environmental Technology(PPC2016007) ; China Postdoctoral Science Foundation(2016M592400) ; China Postdoctoral Science Foundation(2016M592400) ; Fundamental Research Funds for the Central Universities(WUT: 2017IVB012) ; Fundamental Research Funds for the Central Universities(WUT: 2017IVB012) ; U1662134 ; U1662134 ; 2017CFB487) ; 2017CFB487) ; 51472190 ; 51472190 ; 51611530672 ; 51611530672 ; 21711530705 ; 21711530705 ; 51503166 ; 51503166 ; 51602236 ; 51602236 ; 21706199) ; 21706199)
DOI10.1016/j.nanoen.2018.02.021
WOS KeywordINTERFACIAL CHARGE-TRANSFER ; TIO2 NANOTUBE ARRAY ; IN-SITU ; H-2 EVOLUTION ; ENHANCED PHOTOACTIVITY ; TITANIUM-DIOXIDE ; Z-SCHEME ; CDS ; DRIVEN ; HYBRID
Indexed BySCI
Language英语
Funding OrganizationNational Key R&D Program of China(2017YFC1103800) ; National Key R&D Program of China(2017YFC1103800) ; Program for Changjiang Scholars and Innovative Research Team in University(IRT_15R52) ; Program for Changjiang Scholars and Innovative Research Team in University(IRT_15R52) ; National Natural Science Foundation of China(U1663225 ; National Natural Science Foundation of China(U1663225 ; International Science & Technology Cooperation Program of China(2015DFE52870) ; International Science & Technology Cooperation Program of China(2015DFE52870) ; Natural Science Foundation of Hubei Province(2016CFA033 ; Natural Science Foundation of Hubei Province(2016CFA033 ; Open Project Program of State Key Laboratory of Petroleum Pollution Control CNPC Research Institute of Safety and Environmental Technology(PPC2016007) ; Open Project Program of State Key Laboratory of Petroleum Pollution Control CNPC Research Institute of Safety and Environmental Technology(PPC2016007) ; China Postdoctoral Science Foundation(2016M592400) ; China Postdoctoral Science Foundation(2016M592400) ; Fundamental Research Funds for the Central Universities(WUT: 2017IVB012) ; Fundamental Research Funds for the Central Universities(WUT: 2017IVB012) ; U1662134 ; U1662134 ; 2017CFB487) ; 2017CFB487) ; 51472190 ; 51472190 ; 51611530672 ; 51611530672 ; 21711530705 ; 21711530705 ; 51503166 ; 51503166 ; 51602236 ; 51602236 ; 21706199) ; 21706199) ; National Key R&D Program of China(2017YFC1103800) ; National Key R&D Program of China(2017YFC1103800) ; Program for Changjiang Scholars and Innovative Research Team in University(IRT_15R52) ; Program for Changjiang Scholars and Innovative Research Team in University(IRT_15R52) ; National Natural Science Foundation of China(U1663225 ; National Natural Science Foundation of China(U1663225 ; International Science & Technology Cooperation Program of China(2015DFE52870) ; International Science & Technology Cooperation Program of China(2015DFE52870) ; Natural Science Foundation of Hubei Province(2016CFA033 ; Natural Science Foundation of Hubei Province(2016CFA033 ; Open Project Program of State Key Laboratory of Petroleum Pollution Control CNPC Research Institute of Safety and Environmental Technology(PPC2016007) ; Open Project Program of State Key Laboratory of Petroleum Pollution Control CNPC Research Institute of Safety and Environmental Technology(PPC2016007) ; China Postdoctoral Science Foundation(2016M592400) ; China Postdoctoral Science Foundation(2016M592400) ; Fundamental Research Funds for the Central Universities(WUT: 2017IVB012) ; Fundamental Research Funds for the Central Universities(WUT: 2017IVB012) ; U1662134 ; U1662134 ; 2017CFB487) ; 2017CFB487) ; 51472190 ; 51472190 ; 51611530672 ; 51611530672 ; 21711530705 ; 21711530705 ; 51503166 ; 51503166 ; 51602236 ; 51602236 ; 21706199) ; 21706199) ; National Key R&D Program of China(2017YFC1103800) ; National Key R&D Program of China(2017YFC1103800) ; Program for Changjiang Scholars and Innovative Research Team in University(IRT_15R52) ; Program for Changjiang Scholars and Innovative Research Team in University(IRT_15R52) ; National Natural Science Foundation of China(U1663225 ; National Natural Science Foundation of China(U1663225 ; International Science & Technology Cooperation Program of China(2015DFE52870) ; International Science & Technology Cooperation Program of China(2015DFE52870) ; Natural Science Foundation of Hubei Province(2016CFA033 ; Natural Science Foundation of Hubei Province(2016CFA033 ; Open Project Program of State Key Laboratory of Petroleum Pollution Control CNPC Research Institute of Safety and Environmental Technology(PPC2016007) ; Open Project Program of State Key Laboratory of Petroleum Pollution Control CNPC Research Institute of Safety and Environmental Technology(PPC2016007) ; China Postdoctoral Science Foundation(2016M592400) ; China Postdoctoral Science Foundation(2016M592400) ; Fundamental Research Funds for the Central Universities(WUT: 2017IVB012) ; Fundamental Research Funds for the Central Universities(WUT: 2017IVB012) ; U1662134 ; U1662134 ; 2017CFB487) ; 2017CFB487) ; 51472190 ; 51472190 ; 51611530672 ; 51611530672 ; 21711530705 ; 21711530705 ; 51503166 ; 51503166 ; 51602236 ; 51602236 ; 21706199) ; 21706199) ; National Key R&D Program of China(2017YFC1103800) ; National Key R&D Program of China(2017YFC1103800) ; Program for Changjiang Scholars and Innovative Research Team in University(IRT_15R52) ; Program for Changjiang Scholars and Innovative Research Team in University(IRT_15R52) ; National Natural Science Foundation of China(U1663225 ; National Natural Science Foundation of China(U1663225 ; International Science & Technology Cooperation Program of China(2015DFE52870) ; International Science & Technology Cooperation Program of China(2015DFE52870) ; Natural Science Foundation of Hubei Province(2016CFA033 ; Natural Science Foundation of Hubei Province(2016CFA033 ; Open Project Program of State Key Laboratory of Petroleum Pollution Control CNPC Research Institute of Safety and Environmental Technology(PPC2016007) ; Open Project Program of State Key Laboratory of Petroleum Pollution Control CNPC Research Institute of Safety and Environmental Technology(PPC2016007) ; China Postdoctoral Science Foundation(2016M592400) ; China Postdoctoral Science Foundation(2016M592400) ; Fundamental Research Funds for the Central Universities(WUT: 2017IVB012) ; Fundamental Research Funds for the Central Universities(WUT: 2017IVB012) ; U1662134 ; U1662134 ; 2017CFB487) ; 2017CFB487) ; 51472190 ; 51472190 ; 51611530672 ; 51611530672 ; 21711530705 ; 21711530705 ; 51503166 ; 51503166 ; 51602236 ; 51602236 ; 21706199) ; 21706199)
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS SubjectChemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied
WOS IDWOS:000430057000002
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:63[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.apm.ac.cn/handle/112942/12909
Collection中国科学院武汉物理与数学研究所
Corresponding AuthorYang, Xiao-Yu; Su, Bao-Lian
Affiliation1.Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, 122 Luoshi Rd, Wuhan 430070, Hubei, Peoples R China
2.Univ Antwerp, Dept Biosci Engn, Res Grp Sustainable Energy & Air Purificat DuEL, Antwerp, Belgium
3.Univ Littoral Cote dOpale, UCEIV, 145 Ave Maurice Schuman, F-59140 Dunkerque, France
4.Univ Antwerp, EMAT Electron Microscopy Mat Sci, Groenenborgerlaan 171, B-2020 Antwerp, Belgium
5.Petrochem Res Inst PetroChina, Beijing 102206, Peoples R China
6.Chinese Acad Sci, Natl Ctr Magnet Resonance Wuhan, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Inst Phys & Math, Wuhan, Hubei, Peoples R China
7.Univ Namur, Lab Inorgan Mat Chem CMI, 61 Rue Bruxelles, B-5000 Namur, Belgium
Recommended Citation
GB/T 7714
Lu, Yi,Cheng, Xiu,Tian, Ge,et al. Hierarchical CdS/m-TiO2/G ternary photocatalyst for highly active visible light-induced hydrogen production from water splitting with high stability[J]. NANO ENERGY,2018,47:8-17.
APA Lu, Yi.,Cheng, Xiu.,Tian, Ge.,Zhao, Heng.,He, Li.,...&Su, Bao-Lian.(2018).Hierarchical CdS/m-TiO2/G ternary photocatalyst for highly active visible light-induced hydrogen production from water splitting with high stability.NANO ENERGY,47,8-17.
MLA Lu, Yi,et al."Hierarchical CdS/m-TiO2/G ternary photocatalyst for highly active visible light-induced hydrogen production from water splitting with high stability".NANO ENERGY 47(2018):8-17.
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